Cupric Oxide, ACS (CAS: 1317-38-0)

Introduction

Cupric oxide (CuO) is a black, inorganic compound of copper and oxygen. It is widely used in various industrial, scientific, and technological applications. The ACS (American Chemical Society) grade ensures its high purity, making it suitable for laboratory and analytical use.

Chemical and Physical Properties

Chemical Formula and Structure

Formula: CuO
Molecular Weight: 79.55 g/mol
CAS Number: 1317-38-0
Appearance: Black or brownish-black powder
Solubility: Insoluble in water; soluble in acids and ammonium hydroxide
Density: 6.31 g/cm³
Melting Point: 1,326°C (2,419°F)
Boiling Point: Decomposes before boiling

Production Methods

Thermal Oxidation

Cupric oxide can be produced by heating copper metal or cuprous oxide (Cu2O) in the presence of oxygen:
\[ 2Cu + O_2 \rightarrow 2CuO \]

Precipitation Method

Cupric oxide can also be obtained by treating copper salts (such as copper sulfate) with an alkaline solution, followed by heating:
\[ Cu(OH)_2 \rightarrow CuO + H_2O \]

Applications

Industrial Uses

Ceramic and Glass Manufacturing: Used as a colorant to produce blue, green, and turquoise hues in ceramics and glass.
Catalysts: Plays a role in oxidation reactions, including the removal of carbon monoxide in gas purification processes.
Electronics: Used in semiconductor applications and superconductors.
Pigments: Provides black pigmentation in paints, plastics, and coatings.

Laboratory and Scientific Applications

Analytical Reagents: Used as a reagent in chemical analysis and research.
Chemical Synthesis: Serves as a precursor for other copper-based compounds.
Battery Technology: Employed in lithium-ion and alkaline batteries.

Safety and Handling

Hazards

Inhalation: Can cause respiratory irritation if inhaled in powder form.
Skin Contact: May cause irritation upon prolonged contact.
Eye Contact: Causes eye irritation upon direct exposure.
Environmental Impact: Toxic to aquatic life in high concentrations.

Storage and Disposal

Storage: Keep in a cool, dry, and well-ventilated area. Store in tightly sealed containers away from incompatible substances such as strong acids and reducing agents.
Disposal: Follow local regulations for disposal of heavy metal compounds. Do not release into waterways or soil.

Conclusion

Cupric oxide (CuO) is an essential compound with widespread applications in industry, science, and technology. Its high purity, as indicated by the ACS grade, makes it particularly valuable for laboratory research and chemical processes. Proper handling and storage ensure safety and compliance with environmental standards.